Promethium energy level diagram

Energy levels and transitions of neutral promethium (Pm I): the 18 strongest classified lines below 2 µm from the NIST Atomic Spectra Database and the 25 levels they connect, each line with its vacuum wavelength, frequency and, for 0 of them, the reduced dipole matrix element derived from the NIST transition rate. Measured lifetimes, transition rates, hyperfine constants and isotope shifts from the literature are included, each with its citation.

Hover a line or a level to isolate it, click to keep it selected. Scroll to zoom, drag to move.

Download: diagram (PDF) diagram (SVG) transitions (CSV) levels (CSV) source code

Key transitions of promethium

λ, ν from NIST level energies unless a measured frequency for this isotope is available. A: measured value or NIST. Γ/2π: natural linewidth of the upper level, 1/(2πτ).

¹⁴⁷Pm hyperfine structure (I = 7/2)

Measured A, B constants; sources in the data file.

Isotope shifts

Shift = ν(first isotope) − ν(second isotope).

Closed and nearly closed transitions of promethium

A transition is closed when its upper level can decay only to the level it was excited from, so the atom keeps scattering photons. “closed”: among the levels NIST lists, no other level below the upper level has the opposite parity and |ΔJ| ≤ 1, so no other electric-dipole decay exists. Otherwise the leak is the sum of the branching ratios of the other decay lines of the upper level (or 1 − branching ratio where that of the line itself has been measured), and the number of photons is 1 / leak. “≥” and “≤”: at least one possible decay path has no listed rate, so the leak is a lower limit. These numbers are derived from the branching ratios, lifetimes and rates of this page, not measured as such; the tag names the weakest of the inputs, * marks theory and ≈ a model or semi-empirical calculation. Listed: lines that start on the ground level or on a metastable level and leak at most 10 %, unless more than three possible decay paths have no listed rate. Fine-structure levels only: hyperfine and Zeeman dark states and forbidden decays without a listed rate are not considered. Select a line in the diagram for the full list of its leak channels.

Listed Pm transitions below 2 µm

Reduced dipole matrix elements follow the convention A = ω³|d|²/(3πε₀ħc³(2J′+1)), with J′ the upper level. Tags show where a number comes from: measured, NIST compilation, high-accuracy theory, or a model calculation.

Pm energy levels

Pm⁺ ionisation limit 45020.80 cm⁻¹ = 5.58187 eV (222.120 nm)

Sources

• Budick, Marrus, Phys. Rev. 132, 723 (1963), abstract
• NIST ASD level energies
• Studer, Ulrich, Braccini, Carzaniga, Dressler, Eberhardt, Heinke, Koester, Raeder, Wendt,…
• Studer, Ulrich, Braccini, Carzaniga, Dressler, Eberhardt, Heinke, Koester, Raeder, Wendt,…

All hyperfine constants and isotope shifts are from one experiment (in-source resonance-ionisation spectroscopy, PI-LIST, Mainz), linewidth 100-250 MHz. Errors include the authors' extra 1 MHz (A) and 10 MHz (B). B of the 21348.22 and 22080.08 levels for 143-146Pm are dependent fit parameters. Isotope-shift keys follow the schema: nu(first) - nu(second), i.e. nu(147) - nu(A'). Upper-level J values (5/2 for 22080.08, 7/2 for 21348.22) were read from the paper's Fig. 3 and agree with NIST. Level energies of the ionisation schemes were read from an equation image in the article. Neither the 452 nm nor the 468 nm line is among the transitions the site currently draws (those are the strongest NIST lines 473-515 nm), for which no measured data beyond NIST exist.

Atoms with measured data

• Lithium-632 levels, 85 lines
• Lithium-732 levels, 85 lines
• Beryllium-917 levels, 26 lines
• Sodium-2336 levels, 106 lines
• Magnesium-2418 levels, 61 lines
• Magnesium-2518 levels, 61 lines
• Potassium-3934 levels, 84 lines
• Potassium-4034 levels, 84 lines
• Potassium-4134 levels, 84 lines
• Calcium-4035 levels, 61 lines
• Calcium-4335 levels, 61 lines
• Chromium-5256 levels, 87 lines
• Chromium-5356 levels, 87 lines
• Rubidium-8536 levels, 94 lines
• Rubidium-8736 levels, 94 lines
• Strontium-8440 levels, 70 lines
• Strontium-8640 levels, 70 lines
• Strontium-8740 levels, 70 lines
• Strontium-8840 levels, 70 lines
• Cadmium-11115 levels, 21 lines
• Cadmium-11315 levels, 21 lines
• Cadmium-11415 levels, 21 lines
• Caesium-13331 levels, 79 lines
• Barium-13744 levels, 89 lines
• Barium-13844 levels, 89 lines
• Dysprosium-16139 levels, 55 lines
• Dysprosium-16239 levels, 55 lines
• Dysprosium-16339 levels, 55 lines
• Dysprosium-16439 levels, 55 lines
• Erbium-16673 levels, 90 lines
• Erbium-16773 levels, 90 lines
• Erbium-16873 levels, 90 lines
• Thulium-16972 levels, 73 lines
• Ytterbium-17118 levels, 26 lines
• Ytterbium-17318 levels, 26 lines
• Ytterbium-17418 levels, 26 lines
• Mercury-19927 levels, 47 lines
• Mercury-20127 levels, 47 lines
• Mercury-20227 levels, 47 lines

All elements: periodic table